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Chemistry · Glossary

What is Addition polymer, condensation polymer?

Also known as: addition polymer · condensation polymer

Definition 49.5 School Chemistry — Grades 1 to 12 · Chapter 49 — Polymers

An addition polymer forms by additions of monomers carrying a C=C\ce{C=C} double bond, with no other product: its repeat unit has the same atoms as the monomer. A condensation polymer forms by reactions between two functional groups that join two monomers and release a small molecule, usually water, at each link.

monomerpolymerrepeat unituses
ethene CHX2=CHX2\ce{CH2=CH2}polyethene (PE)−CHX2−CHX2X−\ce{-CH2-CH2-}bags, bottles
chloroethene CHX2=CHCl\ce{CH2=CHCl}poly(vinyl chloride) (PVC)−CHX2−CHClX−\ce{-CH2-CHCl-}pipes, frames
phenylethene CHX2=CH−CX6HX5\ce{CH2=CH-C6H5}polystyrene (PS)−CHX2−CH(CX6HX5)X−\ce{-CH2-CH(C6H5)-}cups, foam
tetrafluoroethene CFX2=CFX2\ce{CF2=CF2}PTFE−CFX2−CFX2X−\ce{-CF2-CF2-}non-stick pans
Four addition polymers. In each, the double bond of the monomer opens, and its two carbons join the chain.
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