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Chemistry · Glossary

What is Baeyer–Villiger oxidation?

Also known as: Baeyer--Villiger oxidation

Definition 27.19 University Chemistry — Year 3 · Chapter 27 — Radicals, Carbenes and Rearrangements

The Baeyer–Villiger oxidation turns a ketone into an ester, or a cyclic ketone into a lactone, with a peroxy acid: the peroxy acid adds to the carbonyl group, then a group on the carbonyl carbon migrates to the nearer peroxide oxygen as a carboxylate leaves.

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