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Chemistry · Glossary

What is Canonical partition function?

Definition 10.20 University Chemistry — Year 3 · Chapter 10 — Statistical Thermodynamics: Partition Functions

The canonical partition function of a system at temperature TT and volume VV is the sum Q=∑se−Es/kTQ = \sum_s\eu^{-E_s/kT} over all the states ss of the whole system, of energies EsE_s.

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