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Chemistry · Glossary

What is Centrifugal distortion constant?

Definition 6.6 University Chemistry — Year 3 · Chapter 6 — Rotational and Vibrational Spectroscopy

A rotating bond stretches; the levels become F(J)=BJ(J+1)−DJ2(J+1)2F(J) = BJ(J+1) - DJ^2(J+1)^2, where DD is the centrifugal distortion constant, and the lines 2B(J+1)−4D(J+1)32B(J+1) - 4D(J+1)^3 close up slowly at high JJ.

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