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Chemistry · Glossary

What is Chemical shift, shielding, equivalent protons?

Also known as: chemical shift · shielding · equivalent protons

Definition 17.4 University Chemistry — Year 1 · Chapter 17 — Spectroscopy for Structure

The chemical shift of a proton is δ=(ν−νref)/ν0×106\delta = (\nu - \nu_{\text{ref}})/\nu_0 \times 10^6, in ppm\mathrm{ppm}, where ν\nu is its resonance frequency, νref\nu_{\text{ref}} that of the protons of tetramethylsilane and ν0\nu_0 the operating frequency of the spectrometer. The reduction of the field at a nucleus by its electrons is its shielding: electron-withdrawing neighbours (O, halogens, C=O) deshield a proton and raise its δ\delta. Equivalent protons are protons exchanged by a symmetry of the molecule or by a fast rotation; they have the same shift.

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