The chemical shift of a proton is , in , where is its resonance frequency, that of the protons of tetramethylsilane and the operating frequency of the spectrometer. The reduction of the field at a nucleus by its electrons is its shielding: electron-withdrawing neighbours (O, halogens, C=O) deshield a proton and raise its . Equivalent protons are protons exchanged by a symmetry of the molecule or by a fast rotation; they have the same shift.
Chemistry · Glossary
What is Chemical shift, shielding, equivalent protons?
Also known as: chemical shift · shielding · equivalent protons