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Chemistry · Glossary

What is Denticity?

Also known as: monodentate ligand · bidentate ligand · bridging ligand · ambidentate ligand

Definition 18.3 University Chemistry — Year 2 · Chapter 18 — Transition Metals and Coordination Complexes

The denticity of a ligand is the number of its atoms bound to the same central atom. A monodentate ligand binds through one atom (HX2O\ce{H2O}, NHX3\ce{NH3}, ClX−\ce{Cl-}, CO\ce{CO}), a bidentate ligand through two (ethane-1,2-diamine, written en; the ethanedioate ion, ox). A bridging ligand binds to two metal atoms at once. An ambidentate ligand can bind through either of two different atoms, such as the nitrite ion (through N or O) or thiocyanate (through S or N).

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