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Chemistry · Glossary

What is Disproportionation, comproportionation?

Also known as: disproportionation · comproportionation

Definition 14.8 University Chemistry — Year 1 · Chapter 14 — E–pH Diagrams

Disproportionation is the reaction of a species with itself, one part being oxidised and the other reduced: 2 CuX+→CuX2++Cu\ce{2Cu+ -> Cu^2+ + Cu}. The reverse, two species of the same element giving one of intermediate oxidation number, is comproportionation: 2 FeX3++Fe→3 FeX2+\ce{2Fe^3+ + Fe -> 3Fe^2+}.

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