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Chemistry · Glossary

What is Dissociative, associative and interchange mechanisms?

Also known as: dissociative mechanism · associative mechanism · interchange mechanism

Definition 19.5 University Chemistry — Year 3 · Chapter 19 — Reaction Mechanisms of Complexes

In a dissociative mechanism (D) the leaving ligand departs first, giving an intermediate of lower coordination number; in an associative mechanism (A) the entering ligand binds first, giving an intermediate of higher coordination number; in an interchange mechanism (I) the two ligands exchange in a single step, with a bond-breaking (IdI_d) or bond-making (IaI_a) character.

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