All books

Professional

Apps About Coach Log in Start reading

Chemistry · Glossary

What is Ellingham approximation?

Definition 2.17 University Chemistry — Year 2 · Chapter 2 — Entropy and Free Energy of Reaction

The Ellingham approximation treats ΔrH∘\Delta_r H^\circ and ΔrS∘\Delta_r S^\circ as independent of the temperature over an interval containing no change of state. Then ΔrG∘(T)=ΔrH∘−TΔrS∘\Delta_r G^\circ(T) = \Delta_r H^\circ - T\Delta_r S^\circ is a straight line in TT, of slope −ΔrS∘-\Delta_r S^\circ.

Read in context →