All books

Professional

Apps About Coach Log in Start reading

Chemistry · Glossary

What is Equilibrium isotope effect, fractionation factor, δ value?

Also known as: equilibrium isotope effect · fractionation factor · delta value

Definition 11.15 University Chemistry — Year 3 · Chapter 11 — Statistical Thermodynamics Applied

The equilibrium isotope effect of a reaction is the ratio Klight/KheavyK_{\mathrm{light}}/K_{\mathrm{heavy}} of its equilibrium constants with the light and the heavy isotope. The fractionation factor between two phases or compounds A and B is αA/B=RA/RB\alpha_{\mathrm{A/B}} = R_{\mathrm A}/R_{\mathrm B}, where RR is the ratio of the heavy to the light isotope (for example X18X2218O/X16X2216O\ce{^{18}O}/\ce{^{16}O}). The δ\delta value of a sample is δ=(Rsample/Rstandard−1)×1000\delta = (R_{\mathrm{sample}}/R_{\mathrm{standard}} - 1) \times 1000, in per mil (‰).

Read in context →