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Chemistry · Glossary

What is Exchange current density, transfer coefficient, standard rate constant?

Also known as: exchange current density · transfer coefficient · standard rate constant

Definition 15.4 University Chemistry — Year 3 · Chapter 15 — Electrode Kinetics and Electroanalysis

At equilibrium the anodic and cathodic currents are equal and opposite; their common magnitude per unit area is the exchange current density j0j_0. The transfer coefficient α\alpha (0<α<10 < \alpha < 1) is the fraction of the electrical energy nFηnF\eta that lowers the barrier of the cathodic reaction. The standard rate constant k∘k^\circ is the common value of the cathodic and anodic rate constants at the formal potential E∘′E^{\circ\prime}.

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