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Chemistry · Glossary

What is Inductive effect?

Definition 18.1 University Chemistry — Year 1 · Chapter 18 — Electronic Effects and Reactive Intermediates

The inductive effect is the shift of electron density along σ\sigma bonds towards an electronegative atom or group. An attracting group (F, Cl, O, NOX2\ce{NO2}, CFX3\ce{CF3}) has a −I-I effect; alkyl groups and negatively charged atoms push electrons, a +I+I effect. The effect weakens quickly with the number of bonds in between.

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