Olefin metathesis is the exchange of the alkylidene halves of two alkenes, , catalysed by metal carbene complexes through a metallacyclobutane, a four-membered ring of the metal and three carbons. Its synthetic forms are ring-closing metathesis (RCM), which joins two alkene ends of one molecule into a ring with loss of ethene, ring-opening metathesis polymerisation (ROMP) of strained cyclic alkenes, and cross metathesis between two different alkenes.
Chemistry · Glossary
What is Olefin metathesis?
Also known as: metallacyclobutane · ring-closing metathesis · ring-opening metathesis polymerisation · cross metathesis