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Chemistry · Glossary

What is Photosensitisation, singlet oxygen?

Also known as: photosensitiser · photosensitisation · triplet energy transfer · singlet oxygen

Definition 14.10 University Chemistry — Year 3 · Chapter 14 — Photochemistry

A photosensitiser is a molecule that absorbs light and transfers the energy or an electron to another molecule, which does not itself absorb: this is photosensitisation. In triplet energy transfer the triplet state of the sensitiser, formed by intersystem crossing, gives its energy to the acceptor on contact, leaving the acceptor in its triplet state. Singlet oxygen is the lowest excited state of OX2\ce{O2}, 1Δg{}^1\Delta_g, formed this way from ground-state 3Σg−{}^3\Sigma_g^- oxygen.

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