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Chemistry · Glossary

What is Pre-equilibrium approximation?

Definition 9.8 University Chemistry — Year 1 · Chapter 9 — Reaction Mechanisms: Elementary Steps and Approximations

In the pre-equilibrium approximation, a fast reversible step that precedes the rate-determining step is assumed to remain at equilibrium all along: the concentrations of its species obey its equilibrium constant K1=k1/k−1K_1 = k_1/k_{-1}.

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