The rotational constant of a linear molecule is , in (or in hertz), so that its rotational levels are in wavenumbers. Molecules that differ only in the isotopes of their atoms are isotopologues (, ); in the Born–Oppenheimer approximation they share the same bond lengths and force constants.
Chemistry · Glossary
What is Rotational constant, isotopologue?
Also known as: rotational constant · isotopologue