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Chemistry · Glossary

What is Suprafacial and antarafacial?

Also known as: suprafacial · antarafacial

Definition 26.3 University Chemistry — Year 3 · Chapter 26 — Pericyclic Reactions

A component reacts suprafacially when its two new bonds form, or its two old ones break, on the same face of its π\pi system (or with retention at a σ\sigma bond), and antarafacially when they are on opposite faces (or with inversion).

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