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Chemistry · Glossary

What is Tacticity?

Also known as: isotactic · syndiotactic · atactic

Definition 29.16 University Chemistry — Year 2 · Chapter 29 — Polymers: Synthesis, Structure and Properties

In a vinyl polymer −[CHX2−CHR]XnX−\ce{-[CH2-CHR]_n-}, every CHR\ce{CHR} carbon is a stereocentre. The tacticity describes their relative configurations along the chain drawn as a planar zig-zag: in an isotactic chain all the R\ce{R} groups lie on the same side of the plane, in a syndiotactic chain they alternate, and in an atactic chain they are placed at random.

Polypropene drawn as a zig-zag in the plane of the page; each methyl group is a wedge (towards the reader) or a hashed wedge (away). Isotactic: all methyls on one side; syndiotactic: alternating; atactic: irregular.
Polypropene drawn as a zig-zag in the plane of the page; each methyl group is a wedge (towards the reader) or a hashed wedge (away). Isotactic: all methyls on one side; syndiotactic: alternating; atactic: irregular.
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