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Chemistry · Glossary

What is Two-dimensional spectrum, cross peak, diagonal peak?

Also known as: two-dimensional spectrum · cross peak · diagonal peak

Definition 8.17 University Chemistry — Year 3 · Chapter 8 — NMR in Depth: Pulses, Relaxation and 2D

A two-dimensional spectrum is recorded by repeating a pulse sequence with an incremented delay t1t_1 before the acquisition time t2t_2; a double Fourier transform gives a map of intensity against two frequencies. A cross peak at (δ1,δ2)(\delta_1, \delta_2) shows that the nuclei at δ1\delta_1 and δ2\delta_2 are connected (by a coupling or by proximity); a diagonal peak at (δ,δ)(\delta, \delta) belongs to a single nucleus.

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