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Chemistry · Glossary

What is Activated complex?

Definition 12.4 University Chemistry — Year 3 · Chapter 12 — Theories of Reaction Rates

The activated complex of an elementary step is the set of configurations of the reacting system in a thin slice around the saddle point, perpendicular to the minimum energy path; it is treated as a species ABX‡\ce{AB^{\ddagger}}, with its own partition function.

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