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Chemistry · Glossary

What is Characteristic temperatures?

Also known as: characteristic rotational temperature · characteristic vibrational temperature

Definition 10.13 University Chemistry — Year 3 · Chapter 10 — Statistical Thermodynamics: Partition Functions

The characteristic rotational temperature of a linear molecule of rotational constant BB is θR=hcB/k\theta_{\mathrm R} = hcB/k; the characteristic vibrational temperature of a vibration of wavenumber ν~\tilde\nu is θV=hcν~/k\theta_{\mathrm V} = hc\tilde\nu/k.

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