The delocalisation energy of a conjugated system is the difference between its energy and that of the same number of isolated double bonds, each with .
Examples
Example 16.14 (Benzene)
Six electrons fill and the pair : . Three isolated double bonds give : the delocalisation energy is , about twice that of the open chain of six carbons, hexatriene (): closing the ring is worth as much again. By symmetry all bond indices are equal (), and so are the six bond lengths, , between those of ethene () and ethane ().