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Chemistry · Glossary

What is Direct and indirect gaps?

Also known as: direct band gap · indirect band gap

Definition 22.9 University Chemistry — Year 3 · Chapter 22 — Solid-State Chemistry: Bands, Defects and Semiconductors

A semiconductor has a direct band gap when the top of its valence band and the bottom of its conduction band occur at the same electron momentum, so that a photon alone can carry an electron across, and an indirect band gap when they do not, so that the transition needs a lattice vibration as well.

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