All books

Professional

Apps About Coach Log in Start reading

Chemistry · Glossary

What is Electrode potential, standard potential?

Also known as: standard hydrogen electrode · electrode potential · standard potential

Definition 13.7 University Chemistry — Year 1 · Chapter 13 — Redox Equilibria and the Nernst Equation

The standard hydrogen electrode is a platinum electrode in contact with hydrogen gas at 1 bar1\,\mathrm{bar} and an ideal solution of HX+\ce{H+} of activity 1. The electrode potential EE of a half-cell is the voltage of the cell formed with the standard hydrogen electrode on the left: E=Vhalf-cell−VSHEE = V_{\text{half-cell}} - V_{\text{SHE}}. When every species of the couple has activity 1, it is the standard potential E∘E^\circ of the couple, a constant at a given temperature.

The standard hydrogen electrode: hydrogen gas bubbles over a platinum plate coated with fine platinum, dipped in a solution where H+ has activity 1. Its couple is H+/H2, of potential 0 by convention.
The standard hydrogen electrode: hydrogen gas bubbles over a platinum plate coated with fine platinum, dipped in a solution where HX+\ce{H+} has activity 1. Its couple is HX+\ce{H+}/HX2\ce{H2}, of potential 0 by convention.
Read in context →