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Chemistry · Glossary

What is Inert-pair effect?

Definition 27.4 University Chemistry — Year 1 · Chapter 27 — The p-Block I: Boron, Carbon and Nitrogen Groups

The inert-pair effect is the increasing stability, going down groups 13 to 15, of the oxidation state two below the group’s highest: thallium(I) rather than (III), lead(II) rather than (IV), bismuth(III) rather than (V). The ns2^2 pair of the heavy elements is held tightly and takes little part in bonding.

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