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Chemistry · Glossary

What is Period, group, block?

Also known as: period · group · block

Definition 2.1 University Chemistry — Year 1 · Chapter 2 — Periodicity

In the periodic table the elements are listed by increasing atomic number ZZ. A period is a row: the elements whose valence shell has the same principal number nn. A group is a column, numbered 1 to 18: the elements with the same valence configuration. A block is the set of elements whose last-filled subshell is of one kind, s, p, d or f.

Examples

Example 2.2 (Reading a position)

Selenium, [Ar] 3d104s24p4[\ce{Ar}]\,3\text{d}^{10} 4\text{s}^2 4\text{p}^4, is in period 4 (valence shell n=4n = 4), in the p block, and in group 16 (two s electrons, ten d and four p: 2+10+42 + 10 + 4); its valence configuration ns2np4n\text{s}^2 n\text{p}^4 is that of oxygen and sulfur above it.

Example 2.24 (Lithium in a battery)

Lithium has the lowest electronegativity of period 2 and loses its 2s electron easily, while it is the lightest metal: it carries the most transferable charge per gram of any element, the reason it powers rechargeable batteries. Its first ionisation energy, 5.39 eV5.39\,\mathrm{eV}, is larger than that of sodium (5.14) or potassium (4.34), yet in water it is the most reducing alkali metal, a paradox resolved by the strong hydration of the small LiX+\ce{Li+} ion (Chapter 13).

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