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Chemistry · Glossary

What is Quantum yield?

Also known as: fluorescence quantum yield

Definition 7.17 University Chemistry — Year 3 · Chapter 7 — Electronic Spectroscopy and Photophysics

The quantum yield of a process that follows the absorption of light is the number of events of that process divided by the number of photons absorbed. The fluorescence quantum yield ΦF\Phi_F is the number of photons emitted as fluorescence per photon absorbed.

Examples

Example 7.23 (Quinine and anthracene)

Quinine sulfate in 0.5 M0.5\,\mathrm{M} sulfuric acid absorbs at 349 nm349\,\mathrm{nm} with ε=5700 L mol−1 cm−1\varepsilon = 5700\,\mathrm{L}\,\mathrm{mol}^{-1}\,\mathrm{cm}^{-1} and fluoresces with ΦF=0.546\Phi_F = 0.546, which makes it the classic standard for relative quantum yields. Anthracene in cyclohexane absorbs at 356 nm356\,\mathrm{nm} and has ΦF=0.36\Phi_F = 0.36; most of the rest of its excited molecules cross to the triplet.

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