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Chemistry · Glossary

What is Sol–gel process?

Also known as: sol--gel process · xerogel · aerogel

Definition 23.3 University Chemistry — Year 3 · Chapter 23 — Inorganic Materials and Nanomaterials

The sol–gel process makes an oxide by hydrolysis and condensation of molecular precursors, usually alkoxides, in solution: the solution becomes a sol of small oxide clusters, then a gel, a continuous solid network filled with liquid. Dried by evaporation, the gel shrinks into a dense xerogel; dried above the critical point of the liquid, which removes it without a liquid–gas interface, it keeps its volume as an aerogel.

Sol–gel chemistry of a silicon alkoxide (R: an alkyl group, ethyl in tetraethyl orthosilicate): water replaces alkoxy groups by hydroxy groups, and two silanols condense into a siloxane bridge. Repeated, the condensations build a three-dimensional silica network. Sol–gel chemistry of a silicon alkoxide (R: an alkyl group, ethyl in tetraethyl orthosilicate): water replaces alkoxy groups by hydroxy groups, and two silanols condense into a siloxane bridge. Repeated, the condensations build a three-dimensional silica network.
Sol–gel chemistry of a silicon alkoxide (R: an alkyl group, ethyl in tetraethyl orthosilicate): water replaces alkoxy groups by hydroxy groups, and two silanols condense into a siloxane bridge. Repeated, the condensations build a three-dimensional silica network.
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