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Chemistry · Glossary

What is Spin–spin coupling, coupling constant, multiplet?

Also known as: spin--spin coupling · multiplet · coupling constant

Definition 17.7 University Chemistry — Year 1 · Chapter 17 — Spectroscopy for Structure

Through the bonds, the magnetic state of a proton slightly changes the field felt by protons on the neighbouring carbons: this spin–spin coupling splits each signal into a multiplet of lines separated by the coupling constant JJ, in hertz. Two protons coupled to each other show the same JJ; equivalent protons do not split each other’s signal.

Proton NMR spectra of ethyl ethanoate (top) and ethanol (bottom) in CDCl3, simulated at 90\, MHz from measured shifts and coupling constants (J = 7.2\, Hz and 7.0\, Hz). The OCH2 quartet is deshielded by the oxygen; in ethanol the OH proton, exchanged quickly between molecules, does not couple and its shift depends on the concentration.
Proton NMR spectra of ethyl ethanoate (top) and ethanol (bottom) in CDClX3\ce{CDCl3}, simulated at 90 MHz90\,\mathrm{MHz} from measured shifts and coupling constants (J=7.2 HzJ = 7.2\,\mathrm{Hz} and 7.0 Hz7.0\,\mathrm{Hz}). The OCHX2\ce{OCH2} quartet is deshielded by the oxygen; in ethanol the OH proton, exchanged quickly between molecules, does not couple and its shift depends on the concentration.
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