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Chemistry · Glossary

What is Step and chain growth?

Also known as: step-growth polymerisation · chain-growth polymerisation

Definition 29.4 University Chemistry — Year 2 · Chapter 29 — Polymers: Synthesis, Structure and Properties

In a step-growth polymerisation, any two molecules carrying complementary functional groups (monomers, oligomers or long chains) can react, and the chains lengthen by joining one another: polyesters, polyamides. In a chain-growth polymerisation, a reactive centre (radical, ion or metal–carbon bond) adds monomer molecules one at a time to the end of a growing chain: the polymers of alkenes.

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