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Chemistry · Glossary

What is Symmetry-adapted combination?

Definition 15.2 University Chemistry — Year 2 · Chapter 15 — Fragment Orbitals and Polyatomic Molecules

A symmetry-adapted combination of equivalent atomic orbitals is a combination that each symmetry operation of the molecule (a reflection in a mirror plane, a rotation about an axis) either leaves unchanged or turns into its opposite, or, for degenerate sets, transforms into combinations of the same set.

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