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Chemistry · Glossary

What is VSEPR model, steric number?

Also known as: VSEPR model · steric number

Definition 3.15 University Chemistry — Year 1 · Chapter 3 — Lewis Structures, Resonance and VSEPR

In the VSEPR model (valence-shell electron-pair repulsion), the pairs around a central atom A repel one another and take the arrangement that keeps them farthest apart. A molecule is written AXXnEXm\ce{AX_nE_m}, where nn is the number of atoms bonded to A (a multiple bond counts once) and mm the number of lone pairs of A. The steric number n+mn + m fixes the arrangement of the pairs: 2 linear, 3 trigonal planar, 4 tetrahedral, 5 trigonal bipyramidal, 6 octahedral. The shape of the molecule is the arrangement of its atoms only.

Shapes predicted by VSEPR. A wedge points towards the reader, a hashed wedge away; plain bonds lie in the plane of the page. Lone pairs of the central atom are shown as pairs of dots; XeF4 is drawn face on, its two lone pairs pointing towards and away from the reader.
Shapes predicted by VSEPR. A wedge points towards the reader, a hashed wedge away; plain bonds lie in the plane of the page. Lone pairs of the central atom are shown as pairs of dots; XeFX4\ce{XeF4} is drawn face on, its two lone pairs pointing towards and away from the reader.
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