Consider atoms with two energy levels , populations (number densities) , , and light of frequency with and spectral energy density (energy per unit volume per unit frequency). Three processes exchange energy:
- absorption: an atom in absorbs a photon and rises to , at the rate per unit volume and time;
- spontaneous emission: an atom in falls to on its own, emitting a photon in a random direction with a random phase, at the rate — is the lifetime of the level;
- stimulated emission: a photon of frequency passing an atom in induces it to fall, emitting a second photon identical to the first (same frequency, direction, phase and polarization), at the rate .
, , are the Einstein coefficients of the transition.