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Chemistry · Glossary

What is Alkane, alkyl group?

Also known as: alkane · alkyl group

Definition 32.4 School Chemistry — Grades 1 to 12 · Chapter 32 — Organic Molecules: Skeletons and Names

An alkane is a compound of carbon and hydrogen whose skeleton is a chain (linear or branched, not a ring) with only single bonds; its molecular formula is CXnHX2n+2\ce{C_{n}H_{2n+2}}. An alkyl group is what remains of an alkane when one hydrogen atom is removed, so that it can be attached to a chain: methyl −CHX3\ce{-CH3}, ethyl −CHX2−CHX3\ce{-CH2-CH3}.

nnnameformulannnameformula
1methaneCHX4\ce{CH4}6hexaneCX6HX14\ce{C6H14}
2ethaneCX2HX6\ce{C2H6}7heptaneCX7HX16\ce{C7H16}
3propaneCX3HX8\ce{C3H8}8octaneCX8HX18\ce{C8H18}
4butaneCX4HX10\ce{C4H10}9nonaneCX9HX20\ce{C9H20}
5pentaneCX5HX12\ce{C5H12}10decaneCX10HX22\ce{C10H22}
The first ten linear alkanes. The name of a chain of nn carbon atoms is the same root followed by -ane; the alkyl group replaces -ane by -yl (methyl, ethyl, propyl…).
Naming a branched alkane: the main chain (numbered), the substituents (circled), the name.
Naming a branched alkane: the main chain (numbered), the substituents (circled), the name.
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