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Chemistry · Glossary

What is Equivalent protons?

Definition 38.3 School Chemistry — Grades 1 to 12 · Chapter 38 — Proton NMR

Protons are equivalent protons if they have the same environment in the molecule, so that they absorb at the same shift. Each group of equivalent protons gives one signal. The three protons of a CHX3\ce{CH3} group are always equivalent.

Examples

Example 38.4 (Counting groups)

Propanone, CHX3−CO−CHX3\ce{CH3-CO-CH3}, has six protons but one group: the two CHX3\ce{CH3} are alike, one on each side of the C=O\ce{C=O}. Ethanol, CHX3−CHX2−OH\ce{CH3-CH2-OH}, has three groups (CHX3\ce{CH3}, CHX2\ce{CH2}, OH\ce{OH}), and ethyl ethanoate, CHX3−CO−O−CHX2−CHX3\ce{CH3-CO-O-CH2-CH3}, three as well: the CHX3\ce{CH3} next to C=O\ce{C=O}, the CHX2\ce{CH2} next to O\ce{O}, and the CHX3\ce{CH3} at the end.

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