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Chemistry · Glossary

What is Ligand-field term?

Definition 18.1 University Chemistry — Year 3 · Chapter 18 — Electronic Spectra and Magnetism of Complexes

A ligand-field term of a complex is a set of degenerate many-electron states labelled by its spin multiplicity and the irreducible representation of the point group to which its orbital part belongs, such as 4^4A2g_{2g} or 4^4T1g_{1g} in an octahedral complex.

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