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Chemistry · Glossary

What is Screening, effective nuclear charge?

Also known as: screening · effective nuclear charge

Definition 2.4 University Chemistry — Year 1 · Chapter 2 — Periodicity

In an atom with several electrons, an electron is attracted by the nucleus, of charge ZeZe, and repelled by the other electrons. The inner electrons partly cancel the attraction of the nucleus: this is screening. The valence electron behaves as if it felt a reduced nuclear charge Z∗eZ^{*}e, the effective nuclear charge, with Z∗<ZZ^{*} < Z. Electrons of an inner shell screen almost completely; electrons of the same shell screen only a little.

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