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Chemistry · Glossary

What is Larmor frequency?

Definition 8.3 University Chemistry — Year 3 · Chapter 8 — NMR in Depth: Pulses, Relaxation and 2D

ν0=γB0/2π\nu_0 = \gamma B_0/2\pi is the Larmor frequency of the nucleus: the frequency of the resonance, and also the frequency at which its magnetic moment precesses about the field.

Examples

Example 8.4 (The common nuclei)

For a spin-12\frac12 nucleus of moment μ\mu, γ/2π=μ/(Ih)=2μ/h\gamma/2\pi = \mu/(Ih) = 2\mu/h. With the measured moments: X1X221H\ce{^1H} 42.58 MHz/T42.58\,\mathrm{MHz}/\mathrm{T}, X19X2219F\ce{^{19}F} 40.08 MHz/T40.08\,\mathrm{MHz}/\mathrm{T}, X31X2231P\ce{^{31}P} 17.25 MHz/T17.25\,\mathrm{MHz}/\mathrm{T}, X13X2213C\ce{^{13}C} 10.71 MHz/T10.71\,\mathrm{MHz}/\mathrm{T}, X15X2215N\ce{^{15}N} −4.32 MHz/T-4.32\,\mathrm{MHz}/\mathrm{T}. A “400 MHz400\,\mathrm{MHz} spectrometer” has B0=9.4 TB_0 = 9.4\,\mathrm{T}: its protons resonate at 400.2 MHz400.2\,\mathrm{MHz}, its carbons at 100.7 MHz100.7\,\mathrm{MHz}.

Example 8.22 (An MRI image)

In magnetic resonance imaging a field gradient makes the Larmor frequency of the water protons depend on position, so that the Fourier transform of the signal is a map of where they are. Contrast comes from relaxation: the repetition time and echo delays are chosen to weight the image by T1T_1 or by T2T_2, which differ between tissues; contrast agents containing gadolinium shorten the T1T_1 of nearby water (Chapter 24).

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