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Chemistry · Glossary

What is Rate law, orders, rate constant?

Also known as: rate law · partial order · overall order · rate constant

Definition 8.4 University Chemistry — Year 1 · Chapter 8 — Chemical Kinetics: Rate Laws

A rate law expresses the rate as a function of the concentrations. A reaction has an order when its rate law takes the form

v=k [A]p [B]q⋯ ;v = k\,[\mathrm{A}]^{p}\,[\mathrm{B}]^{q} \cdots ;

the exponents pp, qq, … are the partial orders with respect to A, B, …, their sum is the overall order, and kk is the rate constant, which depends on temperature only. Orders are found by experiment; they need not equal the stoichiometric coefficients, and they can be fractional or zero.

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