Physics · Glossary

What is System, transformation?

Definition 22.1 University Physics — Year 1 · Chapter 22 — The First Law of Thermodynamics

A thermodynamic system is the matter inside a chosen boundary; everything else is the surroundings. A transformation takes it from an equilibrium state to another. It is quasi-static if the system passes through a succession of equilibrium states (slow enough for PP, TT to be defined throughout), and reversible if, in addition, reversing the external conditions reverses the path (no friction, no finite temperature or pressure gap with the surroundings). Names by what stays constant: isothermal (TT), isobaric (PP), isochoric (VV); adiabatic if no heat is exchanged; monobaric (monothermal) if the external pressure (temperature) is constant, whatever happens inside.

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