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Chemistry · Glossary

What is Bonding pairs and lone pairs?

Also known as: bonding pair · lone pair

Definition 24.2 School Chemistry — Grades 1 to 12 · Chapter 24 — Lewis Structures and the Shape of Molecules

In a molecule, the valence electrons of each atom are grouped in pairs. A bonding pair is shared between two atoms and forms a covalent bond; a lone pair belongs to a single atom and takes no part in a bond.

Examples

Example 24.7 (Carbon dioxide)

COX2\ce{CO2}: 4+2×6=164 + 2 \times 6 = 16 valence electrons, 8 pairs. Single bonds O−C−O\ce{O-C-O} use 2 pairs; 6 lone pairs on the oxygens complete them, but carbon then has only 4 electrons. Turning one lone pair of each oxygen into a shared pair gives two double bonds: each atom now has an octet.

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