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Chemistry · Glossary

What is Conjugated system, chromophore, absorption maximum?

Also known as: conjugated system · chromophore · absorption maximum

Definition 17.2 University Chemistry — Year 1 · Chapter 17 — Spectroscopy for Structure

A conjugated system is a chain of atoms each carrying a pp orbital in a π\pi system, as in alternating double and single bonds (buta-1,3-diene, benzene). The group of atoms responsible for an absorption is its chromophore; the wavelength at which its absorbance is greatest is the absorption maximum, λmax⁡\lambda_{\max}.

Carrots and tomatoes owe their colours to long conjugated molecules, carotenes and lycopene, that absorb blue and green light and let orange and red through.
Carrots and tomatoes owe their colours to long conjugated molecules, carotenes and lycopene, that absorb blue and green light and let orange and red through.
A colour wheel. The colour seen is the complement of the colour absorbed: a solution absorbing in the blue looks orange.
A colour wheel. The colour seen is the complement of the colour absorbed: a solution absorbing in the blue looks orange.
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