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Chemistry · Glossary

What is Reciprocal lattice?

Definition 9.5 University Chemistry — Year 3 · Chapter 9 — Crystallography and X-ray Diffraction

For a lattice of basis vectors a\mathbf a, b\mathbf b, c\mathbf c and cell volume VV, the reciprocal lattice has basis vectors a∗=(b×c)/V\mathbf a^* = (\mathbf b\times\mathbf c)/V, b∗=(c×a)/V\mathbf b^* = (\mathbf c\times\mathbf a)/V, c∗=(a×b)/V\mathbf c^* = (\mathbf a\times\mathbf b)/V, so that a⋅a∗=1\mathbf a\cdot\mathbf a^* = 1 and a⋅b∗=0\mathbf a\cdot\mathbf b^* = 0. Its node Ghkl=ha∗+kb∗+lc∗\mathbf G_{hkl} = h\mathbf a^* + k\mathbf b^* + l\mathbf c^* is perpendicular to the planes (hkl)(hkl), and ∣Ghkl∣=1/dhkl|\mathbf G_{hkl}| = 1/d_{hkl}.

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