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Chemistry · Glossary

What is Relative permittivity?

Definition 4.8 University Chemistry — Year 1 · Chapter 4 — Intermolecular Forces and Solvents

In a medium, the Coulomb force between two charges is divided by a number εr≥1\varepsilon_r \ge 1, the relative permittivity (or dielectric constant) of the medium:

F=∣q1q2∣4πε0εrr2.F = \frac{|q_1 q_2|}{4\pi\varepsilon_0\varepsilon_r r^2} .

It is large for liquids of polar molecules, which orient around the charges and screen them: 78.478.4 for water at 25 ∘C25\,{}^{\circ}\mathrm{C}, 1.891.89 for hexane at 20 ∘C20\,{}^{\circ}\mathrm{C}.

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