The activation energy of a reaction of rate constant is defined by
in . When is independent of , integrating gives , where the constant , of the unit of , is the pre-exponential factor.
Examples
Example 8.19 (A rule of thumb)
For , going from 25 to multiplies by . The familiar rule “ten degrees more, twice as fast” holds near room temperature for reactions of activation energy around ; for larger the factor is larger.