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Chemistry · Glossary

What is Commutator?

Definition 1.5 University Chemistry — Year 3 · Chapter 1 — Quantum Mechanics for Chemists: Model Systems

The commutator of two operators is [A^,B^]=A^B^−B^A^[\hat A,\hat B] = \hat A\hat B - \hat B\hat A. The operators commute if their commutator is zero.

Examples

Example 1.6 (The canonical commutator)

For any function ff, x^p^f=−iℏxf′\hat x\hat pf = -\iu\hbar xf' and p^x^f=−iℏ(f+xf′)\hat p\hat xf = -\iu\hbar(f + xf'). The difference is [x^,p^]f=iℏf[\hat x,\hat p]f = \iu\hbar f, so [x^,p^]=iℏ[\hat x,\hat p] = \iu\hbar: position and momentum do not commute. This single relation underlies the uncertainty principle and, below, the whole spectrum of the harmonic oscillator.

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