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Chemistry · Glossary

What is Crystal, amorphous solid, perfect crystal?

Also known as: crystal · amorphous solid · perfect crystal model

Definition 5.1 University Chemistry — Year 1 · Chapter 5 — Crystals I: The Perfect Crystal and Metals

A crystal is a solid whose particles (atoms, ions or molecules) are arranged in a pattern that repeats periodically in three dimensions. A solid without such long-range order is an amorphous solid (glass, most plastics). The perfect crystal model describes a crystal as infinite and without defects: no missing or extra atoms, no impurities, no boundaries.

Examples

Example 5.21 (Steel)

Carbon, of covalent radius 77 pm77\,\mathrm{pm} (half the C−C\ce{C-C} distance in diamond), is too large for the sites of iron without distortion, but much less so in γ\gamma-iron, whose octahedral sites are the largest. Steel is made by dissolving carbon in hot γ\gamma-iron; quenched, the carbon is trapped as the iron returns to a body-centred structure, which it distorts, and the distorted crystal is hard.

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