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Chemistry · Glossary

What is Formal charge?

Definition 3.2 University Chemistry — Year 1 · Chapter 3 — Lewis Structures, Resonance and VSEPR

The formal charge of an atom in a Lewis structure is

qF=Nv−Nlone−12Nbond,q_F = N_v - N_{\text{lone}} - \tfrac12 N_{\text{bond}},

where NvN_v is the number of valence electrons of the free atom, NloneN_{\text{lone}} the number of electrons in its lone pairs and NbondN_{\text{bond}} the number of electrons in the bonds it forms. It is written ⊕\oplus or ⊖\ominus next to the atom when it is not zero.

Examples

Example 3.5 (Nitric acid)

HNOX3\ce{HNO3}: N=1+5+3×6=24N = 1 + 5 + 3 \times 6 = 24 electrons, 12 pairs. Skeleton: nitrogen central, bonded to three oxygens, one of which carries the hydrogen. Completing octets with single bonds leaves nitrogen with six electrons; one oxygen lone pair becomes an N=O\ce{N=O} bond. Formal charges: nitrogen 5−0−4=+15 - 0 - 4 = +1; the singly bonded oxygen without hydrogen 6−6−1=−16 - 6 - 1 = -1; the others 0. The total is 0, as Proposition 3.3 requires.

Example 3.9 (Ammonia and boron trifluoride)

NHX3+BFX3→HX3NBFX3\ce{NH3 + BF3 -> H3NBF3}. In the adduct, boron completes its octet; nitrogen, which now shares its lone pair, carries the formal charge +1+1 and boron −1-1. Once formed, the N−B\ce{N-B} bond is an ordinary covalent bond.

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