The hybridisation of an atom is a description of its bonds by orbitals pointing along the directions predicted by VSEPR: an atom of steric number 4 is said to be sp (four equivalent orbitals at ), of steric number 3 sp (three orbitals at in a plane, one p orbital left perpendicular to it), of steric number 2 sp (two orbitals at , two p orbitals left). The p orbitals left over form the bonds.
Examples
Example 3.20 (The carbons of organic chemistry)
In ethane each carbon is sp, tetrahedral; in ethene sp, the six atoms in one plane with angles near (measured ); in ethyne sp, the four atoms on one line. The bond lengths shrink from 153.6 to 133.9 to as bonds are added.