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Chemistry · Glossary

What is Hybridisation?

Definition 3.19 University Chemistry — Year 1 · Chapter 3 — Lewis Structures, Resonance and VSEPR

The hybridisation of an atom is a description of its bonds by orbitals pointing along the directions predicted by VSEPR: an atom of steric number 4 is said to be sp3^3 (four equivalent orbitals at 109.5∘109.5^\circ), of steric number 3 sp2^2 (three orbitals at 120∘120^\circ in a plane, one p orbital left perpendicular to it), of steric number 2 sp (two orbitals at 180∘180^\circ, two p orbitals left). The p orbitals left over form the π\pi bonds.

Examples

Example 3.20 (The carbons of organic chemistry)

In ethane each carbon is sp3^3, tetrahedral; in ethene sp2^2, the six atoms in one plane with angles near 120∘120^\circ (measured H−C−H\ce{H-C-H} 117.6∘117.6^\circ); in ethyne sp, the four atoms on one line. The bond lengths shrink from 153.6 to 133.9 to 120.3 pm120.3\,\mathrm{pm} as π\pi bonds are added.

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