When a reactant can give two products by competing paths, the reaction is under kinetic control if the product proportions are fixed by the rates of formation (the product of lower barrier dominates), and under thermodynamic control if the paths are reversible and the system reaches equilibrium (the more stable product dominates).
Examples
Example 9.18 (Choosing the product)
A reactant gives B over a barrier of () and C over a barrier of (). At and short times, with equal pre-exponential factors, B forms times faster than C: kinetic control gives B. At high temperature and long times, B returns over its small reverse barrier, C does not, and the system ends as C: thermodynamic control.